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91.
本文采用直流反应磁控溅射方法,通过溅射(CrMoTaNbV)镶嵌靶和纯Ti靶制备了(CrMoTaNbVTi)N多主元氮化物薄膜。研究了不同氮气流量比RN对(CrMoTaNbVTi)N薄膜的微观结构、力学性能和摩擦学性能的影响。结果表明,当RN=0% 和10%时薄膜为简单的体心立方结构,当RN=20%、30% 和40%时为简单的面心立方结构。随着氮气流量比RN的增大,表面颗粒逐渐减小,断面柱状晶更为致密,同时(CrMoTaNbVTi)N薄膜的残余应力、膜基结合力、硬度和弹性模量逐渐增大,且当RN=40%时达到最大值,分别为-3.3 GPa, 352 mN, 25.6±1.2 GPa 和 278.8±11.2 GP。RN =40%制备的氮化物薄膜具有最小的比磨损率,相较合金薄膜降低了约1个数量级,表现出优异的耐磨损性能。 相似文献
92.
采用无氰电镀工艺在TC4合金表面制备了Cu/石墨复合镀层,研究了镀层的组织结构和摩擦磨损行为。结果表明,采用无氰电镀方法能够在TC4合金表面制备出组织致密且与基体结合紧密的Cu/石墨复合镀层,但增加镀层中石墨的含量会降低镀层与基体合金的结合强度,并导致硬度小幅下降。摩擦磨损实验结果表明,Cu/石墨复合镀层具有优良的摩擦磨损防护性能,归因于石墨有效降低了镀层的摩擦系数和磨损率;对镀层磨损形貌、磨损产物和摩擦系数的综合分析结果表明,纯铜镀层的摩擦磨损机制主要为犁削磨损、黏着磨损和剥层磨损,Cu/石墨复合镀层的磨损机制为轻微的削层磨损和疲劳磨损。 相似文献
93.
《中国有色金属学会会刊》2020,30(9):2369-2380
The local inhomogeneity of the stir zone in friction stir welded face-centered cubic metal was investigated, which has multiple activated slip systems during plastic deformation, by selecting commercial AA1050 aluminum alloy as an ideal experimental material. The local inhomogeneity was evaluated by uniaxial tensile tests using small samples with a 1 mm gauge length. The corresponding microstructural parameters such as grain size, misorientation angle distribution, and micro-texture, were quantified by the backscattered electron diffraction technique. A comprehensive model was used to reveal the microstructure−mechanical property relationship. The experimental results showed that the uniaxial tensile property changes significantly across the weld. The maximum ultimate tensile strength (UTS) occurred in the center of the stir zone, which was 99.0 MPa. The weakest regions were located at the two sides of the stir zone. The largest difference value in UTS reached 14.9 MPa, accounting for 15% of the maximum UTS. The analysis on the structure−mechanical property relationship suggests that the micro-texture change with the location formed during the rotational material flow is the main reason for the local inhomogeneity. 相似文献
94.
《中国有色金属学会会刊》2020,30(12):3254-3262
Rapid-cooling friction-stir-welding (FSW) was used to join AZ31B magnesium alloy plates of 6 mm in thickness. The microstructure and mechanical properties in thickness direction were carefully investigated with electron backscattered diffractometer, and transmission electron microscope. The obtained results showed that ultrafine grains with high dislocation density were obtained in the top region of the weld due to liquid CO2 cooling. A large number of twins and second-phase particles were also induced in these refined grains. The basal texture intensity was significantly reduced due to the appearance of twins. The top region showed the higher strength and elongation compared with the bottom region, and the welding efficiency reached 93%. This work provided a simple and efficient strategy for manufacturing a gradient structure in the FSW Mg alloy joint. 相似文献
95.
研究了固溶及时效处理对铬青铜QCr1铸件力学性能及电导率的影响。研究结果表明,固溶温度不应超过1 030℃,时效处理后强度随时间先升后降,时效温度越高,可达到的强度峰值的时间越短,峰值强度越低。优化后的规范使QCr1铸件的强度及电导率均满足DIN系列相关标准要求。 相似文献
96.
Mechanical behavior of cold-water fish gelatin gels crosslinked with 1,4-butanediol diglycidyl ether
Marina Czerner Mariano Prudente Josefa Fabiana Martucci Federico Rueda Laura Alejandra Fasce 《应用聚合物科学杂志》2020,137(34):48985
In this work, chemical crosslinking with 1,4-butanediol diglycidyl ether (BDDGE) is used as strategy to enhance mechanical performance of fish gelatin (FG) gels in order to meet the properties' range of mammalian gelatin physical gels. Joint analysis of free amino groups, swelling ratio, and total soluble material indicates that crosslinking degree increases with increasing FG concentration and it is favored by a 0.2 BDDGE/FG ratio. Increasing crosslinking degree enhances gel indentation strength and shear modulus (μ) while decreases fracture toughness (GIC). Measured μ and GIC values lies within the range exhibited by mammalian gelatin physical gels, but the relationship between these parameters is opposite. This is due to the different fracture mechanisms occurring in chemically crosslinked and physical gels. 相似文献
97.
The aim of this research is to evaluate the effect of polyphosphoric acid (PPA) on the mechanical performance of styrene–butadiene–styrene (SBS) and styrene–butadiene–rubber (SBR) modified asphalt. Conventional properties, multiple stress creep recovery (MSCR), bending beam rheometer (BBR), and linear amplitude sweep (LAS) tests were conducted to evaluate the performance characteristics of asphalt at different PPA inclusions. Gel-permeation chromatography (GPC), saturates, aromatics, resins, and asphaltenes (SARA), and Fourier transform infrared (FTIR) were carried to reveal the molecular weight, component and infrared spectra of asphalt. Results showed that PPA hardened the asphalt, improved the rutting and fatigue performances of polymer modified asphalt (PMA) binder, but weakened the anti-cracking performances. Besides, storage stability had a significant improvement as the addition of PPA. The addition of PPA brought more macromolecules into asphalt and led to more high-average molecular weight compounds. Furthermore, PPA changed four component ratios of asphalt. Both PMA with or without PPA have similar absorption peaks. This may be due to absorption peak of PMA covered the changes in PPA modification process as the low content of PPA. 0.8% dosage of PPA may be considered optimum for composite modified binder combining the above experimental results for this binder source. 相似文献
98.
Edwin A. Murillo 《应用聚合物科学杂志》2020,137(8):48386
Waterborne star-shaped styrene-alkyd resins (SSARs) were synthesized from a branched alkyd resin (AR) and styrene (St) by miniemulsion polymerization. SSARs are an environmentally friendly material. The ratio of AR to St for obtaining SSARs was as follows: 50:50 (SSAR1), 60:40 (SSAR2), 70:30 (SSAR3), and 80:20 (SSAR4). The conversion percentage was directly proportional to St used, and was higher than 94.0 %. Infrared analysis and protonic nuclear magnetic resonance revealed the reaction between AR and St. The synthesis process also leads to the formation of polystyrene and its concentration increases with the concentration of St. The values of the reacted double-bond fractions were higher than 17.80%. The SSARs drop size was bigger than the particle size. The miniemulsion colloidal stability was good at room temperature. The SSARs zeta potential was between −55 and −90 mV. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48386. 相似文献
99.
《Ceramics International》2020,46(7):9170-9175
NASICON-structured sodium vanadium fluorophosphate has caused widespread concern for sodium energy conversion and storage because of its high voltage platform and high theoretical energy density. However, the inferior electrical conductivity is still a big problem, which greatly prevent the applications of Na3V2(PO4)2F3 material. Herein, the nitrogen-doped graphene-encapsulated Na3V2(PO4)2F3@C (NG-NVPF@C) has been prepared using the sol-gel approach. The physical and electrochemical performances for the resulted NG-NVPF@C composite have been systematically characterized and compared with that of Na3V2(PO4)2F3@C (NVPF@C) in this study. The electrochemical tests demonstrate that the as-fabricated NG-NVPF@C displays higher capacity, superior rate property and better cyclic life than NVPF@C. It displays the discharge capacity of 108.6 mAh g−1 at 5C. Moreover, it also possesses the high capacity of 101.6 mAh g−1 at 10C over 300 cycles with the capacity retention of about 96.5%. The improved properties of NG-NVPF@C electrode are assigned to the constructed conductive network by nitrogen-doped graphene, which can modify the conductivity of Na3V2(PO4)2F3. 相似文献
100.
An integrated model of ultrasonic vibration enhanced friction stir welding (UVeFSW) is developed by integrating the thermal-fluid model with the ultrasonic field model and tool torque model. The tool torque and the heat generation rate at tool/workpiece contact interfaces are coupled with the interfacial temperature, strain rate and ultrasonic energy density. The model is used in quantitatively analysing the effects of ultrasonic vibration on tool torque and thermal processes in friction stir welding (FSW). The results show that ultrasonic vibration reduces the flow stress, which results in a decreasing of tool torque, interfacial heat generation rate and interfacial temperature. The complicated interaction of ultrasonic energy with the thermal processes in FSW leads to a gentle thermal gradient and an enhanced plastic material flow in UVeFSW. The model is validated by a comparison of the calculated thermal cycles and tool torque at various welding parameters with the experimentally measured ones. 相似文献